A unified axiomatic theory that embraces both mechanics and thermodynamics is presented in three parts. It is based on four postulates; three are taken from quantum mechanics, and the fourth is the new disclosure of the existence of quantum states that are stable (Part I). For nonequilibrium and equilibrium states, the theory provides general original results, such as the relation between irreducible density operators and the maximum work that can be extracted adiabatically (Part IIa). For stable equilibrium states, it shows (...) for the first time that the canonical and grand canonical distributions are the only stable distributions (Part IIb). The theory discloses the incompleteness of the equation of motion of quantum mechanics not only for irreversible processes but, more significantly, for reversible processes (Part IIb). It establishes the operational meaning of an irreducible density operator and irreducible dispersions associated with any state, and reveals the relationship between such dispersions and the second law (Part III). (shrink)

This part of the paper concludes the presentation of the unified theory. It is shown that the theory requires the existence of, and applies only to, irreducible quantal dispersions associated with pure or mixed states. Two experimental procedures are given for the operational verification of such dispersions. Because the existence of irreducible dispersions associated with mixed states is required by Postulate 4 of the theory, and because Postulate 4 expresses the basic implications of the second law of classical thermodynamics, it (...) is concluded that the second law is a manifestation of phenomena characteristic of irreducible quantal dispersions associated with the elementary constituents of matter. (shrink)

Part IIb presents some of the most important theorems for stable equilibrium states that can be deduced from the four postulates of the unified theory presented in Part I. It is shown for the first time that the canonical and grand canonical distributions are the only distributions that are stable. Moreover, it is shown that reversible adiabatic processes exist which cannot be described by the dynamical equation of quantum mechanics. A number of conditions are discussed that must be satisfied by (...) the general equation of motion which is yet to be discovered. (shrink)

Part II of this three-part paper presents some of the most important theorems that can be deduced from the four postulates of the unified theory discussed in Part I. In Part IIa, it is shown that the maximum energy that can be extracted adiabatically from any system in any state is solely a function of the density operator $\hat \rho$ associated with the state. Moreover, it is shown that for any state of a system, nonequilibrium, equilibrium or stable equilibrium, a (...) unique propertyS exists which is proportional to the total energy of the system minus the maximum energy that can be extracted adiabatically from the system in combination with a reservoir. For statistically independent systems, propertyS is extensive, it is invariant during all reversible processes, and it increases during all irreversible processes. (shrink)